Product ID:MALACHITE GREEN OXALATE CERTIFIED, M9015
MSDS Date:04/01/1999
FSC:6550
NIIN:00N092174
Status Code:A
MSDS Number: CJRCW

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: 21076

Telephone: 314-771-5765

Cage: 21076

MALACHITE GREEN OXALATE

CAS: 2437-29-8

RTECS: BQ1190000

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED. MAY BE
HARMFUL IF INHALED. MAY BE HARMFUL IF ABSORBED THROUGH THE SKIN.
CAUSES SEVERE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MATERIAL
MAY BE IRRITATING TO MUCOUS MEMBR ANES AND UPPER RESPIRATORY TRACT.
TO THE BEST OF MANUFACTURER'S KNOWLEDGE, THE CHEMICAL, PHYSICAL,
AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.

First Aid:EYES/SKIN: FLUSH IMMEDIATELY WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND
SHOES. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RE SPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON
IF CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE
REUSE.

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN
A BAG AND HOLD FOR DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND
WASH SPILL SITE AFT ER MATERIAL PICKUP IS COMPLETE.

Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
TOXIC. SEVERE EYE IRRITANT. KEEP TIGHTLY CLOSED. STORE IN A COOL
DRY PLACE.

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:WEAR CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health

Melt/Freeze Pt:=164.C, 327.2F
Appearance and Odor:GREEN CRYSTALLINE POWDER.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:RTECS #: BQ1190000: AMMONIUM,
(4-(P-(DIMETHYLAMINO)-ALPHA-PHENYLBENZYLIDENE)2,5-CYCLOHEXADIEN-1-Y
LIDDIMETHYL-, OXALATE (2:1), OXALATE (1:1). IRRITATION DATA:
EYE-RABBIT 76 MG/KG SEV, ARTODN 56, 43, 19 84. TOXICITY DATA:
ORAL-RAT LD50: 275 MG/KG, ARTODN 56, 43, 1984. TARGET ORGAN DATA:
BEHAVIORAL (CHANGE IN MOTOR ACTIVITY); GASTROINTESTINAL
(HYPERMOTILITY, DIARRHEA, OTHER CHANGES). ONLY SELECTED REG ISTRY
OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED
HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS.
Federal Regulatory Information:EUROPEAN INFORMATION: HARMFUL. R 22:
HARMFUL IF SWALLOWED. R 41: RISK OF SERIOUS DAMAGE TO EYES. S 45:
IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY (SHOW THE LABEL WHERE POSSIBLE). S 26: IN CASE OF
CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK
MEDICAL ADVICE. S 36/37/39: WEAR SUITABLE PROTECTIVE CLOTHING,
GLOVES AND EYE/FACE PROTECTION. REVIEWS, S TANDARDS, AND
REGULATIONS: OEL=MAK. NOES 1983: HZD X2442; NIS 1; TNF 6; NOS 1;
TNE 112; TFE 41. EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE
1998.
State Regulatory Information: